I see this is an old post but I had the same issue as
Cwoods1405 while on holiday in a very remote location with our 5 month old T6.1 which is driven everyday. I went out one morning and noticed a flat tyre and was pleased with myself that I had ordered a spare alloy/tyre so I set about jacking the car up and loosening the bolts. The alloy did not budge off the wheel hub, the car wavered on the jack so I lowered the Cali and put the bolts back on and slowly moved back and forward to see if this would release the wheel and jacked it back up but no success. I also tried using the spare wheel to 'club' the punctured tyre/alloy wheel to see if I could loosen the wheel but it was totally stuck. In the end I had to call road side assistance which arrived within the hour. Their solution was to take huge swing at the alloy on the inside of the wheel with a large bar. The alloy wheel came off after 2-3 blows but is now marked severely and is probably damaged. The lessons I have from this is that 1) if I ever need assistance at the side of the road again and some fella is going to take a swing at the wheel then put a mat on the inside to protect the wheel, and 2) I now always carry a decent sized rubber mallet which hopefully negates the need of request roadside assistance in the future.
I now have the offending alloy wheel and repaired tyre as my spare because I did not feel comfortable driving on it everyday after the trashing the wheel got from the iron bar, and this was significant because I had the tracking checked and it need to be readjusted.
I understand now that dissimilar metal corrosion is something that can occur so I will be removing all of my wheels and cleaning them up and applying copper grease or silicon to when the hub contacts the alloy. I have never experienced this before & I was really surprised that it could occur in such a new vehicle. I have questioned VW about this as part of the PDI and asked which they do not check and lubricate the hub before handing over the vehicle and they stated it was not done for safety reasons. Frankly Im not impressed.