I am so sorry to hear that, it must be frustrating.
After your hundred mile drive did you camp from it?
Did you put the van in camping mode, run the parking heater, get in and of the drivers door, have you got keyless entry turned on, were you connected to the infotainment system via Bluetooth?
These are all potential power consumers for the starter battery. There’s not a lot of headroom in an AGM battery before you drop to 11v. Could you see the voltage of the starter battery from the app or control panel?
Your leisure batteries are a somewhat different beast, you should have started with 100% after that drive, I tend to press the battery boost button on the dash to make sure it is fully charged - it should show 60 hours or more capacity on the California app.
I’d be interested to hear what you were using in the rear of the van, did you use the inverter? That can be a power hog as it isn’t very efficient for 240v?