Mines a diesel rather than an petrol, but the procedure will be similar.
Firstly some pictures
Here's a useful diagram, item 12 being the thermostat.
https://www.partsbase.org/vw/transporter-tr-eu-1993-12110-coolant-pump/
And here is the location on the engine, item 29 being the location I think.
https://www.partsbase.org/vw/transporter-tr-eu-1993-12145-coolant-hoses-and-pipes/
Procedure is pretty much the same, unbolt the plastic housing and get wet. At least, that is what I did. Have a bucket handy to catch the coolant, it can be reused.
Not sure how much coolant the petrol holds, the diesel holds more coolant than my bucket...
Change the stat (or test the current one, you can test them by dropping them into hot water).
Bolt the housing back on, taking care with the o-ring.
Pour coolant back in via the expansion tank. If it's not got the pink stuff (G12? at least) then consider replacing with new coolant.
Run the engine, ensure the heater is set to it's hottest setting. You can vent air from the system from a little plastic screw in a hose near the expansion tank.
Top up coolant as necessary and replace the lid on the expansion bottle before the water boils.
As an aside, my van reads 70c not 90c. It reads hotter when I go up hill and colder when I go down hill. The engine is running at 90c (fans coming on/off, wax stat opening vanes or rad appropriately. Infra red thermometer showing right water temp). I've tried changing senders, thermostat, radiator and radiator fan switch. Think it's likely an electrical problem. Or someone has fitted an altimeter.
dan