If you are looking at a recent 204, then I think the main thing to check is the roof bellows.
Unless the Cali you are looking has the latest 06S version of the bellows fitted, then they could leak.
I'm not sure when the design change was made from the bellows with the darker coloured inside, to those with a light coloured interior, but my understanding is that the main leakage issues started with that design change. (Hopefully someone can confirm this)
If any van you are viewing has the lighter coloured internal material, then it is easy enough to spot if the latest 06S bellows have been fitted. The vertical side seams will be taped with a clear waterproofing tape.
Here is a photo I copied from another post, showing the taped seam.
Previous reports suggested that not all of the pre 06S version bellows leaked, but for many of us, they did.
Options to resolve the leaks are to either spray with Aquatex (VW would not give a definitive "OK" to do this without invalidating the warranty) or to seek a warranty replacement.
I went down the Aquatex route with my 04S bellows as at the time I wasn't convinced a warranty replacement would be any better. The Aquatex worked perfectly and our Cali has been leak free since April last year.
Given the positive reports on the latest 06S version, I think I would now be pushing for a warranty replacement if I had any further leaks, or if I purchased a van that had a leaking roof.