The system should switch over to charge all of the batteries automatically. There are no switches to change.
Check the following things.
Your cable is OK, but has the breaker on
your supply post tripped?
Provided you have checked the breaker in the back cupboard is on (up) and have checked it is functioning properly when the van in hooked up by pressing the test button, (it will flip down, push up to reset it) then power is getting to the van. I have found this is very sensitive and will trip if something is plugged into the mains socket that it doesn't like. Make sure nothing is plugged in when you hook the Cali up initially
Double check power ie on the van by plugging something (phone charger?) into the 13 amp socket on the end of the kitchen unit. If OK, then power is getting to the van and being distributed.
Than narrows it down to one of two things, it could either be the flight panel or the charger at fault.
On the flight panel look to see if there is a 2 pronged icon displayed (bottom right always and top middle too, if the battery display has been selected) when the power is hooked up. If so then that is OK
The leaves the charger.
Another thread found the charger was unplugged from the mains. This is located under the fridge. It can be seen by peering through the access hole in bottom left side of the left hand cupboard under the hob unit. You will need to get down on your knees to do this. Check the IEC mains plug is fully home.
If that all fails, then it will be a visit to the local VW Van dealer.
Hope that helps.
Alan