Just had a similar problem occur. I have a 65 place T6. Currently on 40k miles
My Cali had sat for 3 weeks whist I had been away on holiday. Came back to the coolant warning light. Popped to my local garage who topped me up with coolant, and told me to keep an eye on level.
About a week later after doing just a few hundred miles, warning light came back on, so called VW assist. The chap who turned up told me the Cali had the same engine as the cars, and it can take up to 30k for the coolant levels to fully settle, as (his words) "despite being vacuum filled, it seems that occasionally there are air locks that take a while to fully clear through".
He was surprised that with my van there was still really good pressure on the top-up cap, and no clear evidence of stone damage, or any other leak. He wanted to recover my Cali to the local van centre there and then, but I was happy to risk another top-up and see what happened. So a full bottle (nearly) or coolant was added.
Well a week later, coolant warning is back on, and the AA are now outside taking my van off to the local VW van centre. It will be interesting to see what they make of it, but thank you for the great advice on this thread, as I might be able to steer them in the right direction (if needed).